Research Interests, Students, and Recent Projects

I study the interaction of hydrous fluids with rocks and minerals. Fluid-rock interactions are ubiquitous on Earth. At the surface of the earth, water plays a key role in weathering, alteration, and precipitation of minerals. Low-temperature minerals like manganese oxides are crucial in cycling and storage of nutrients in soils and scavenging of trace metals in the oceans. These minerals often contain water or hydroxyl groups in their structures.

Fluids also play an important role in high-temperature igneous and metamorphic systems. Water affects the rates of cation and oxygen diffusion in minerals. Mineral melting temperatures are lowered in the presence of water, and fluids are important in many aspects of volcanism (for example, the explosive or effusive nature of an eruption, and melting in the mantle wedge above a subducting slab). Structural water and fluid inclusions within minerals cause hydrolytic weakening of rocks, and influence the electrical conductivity and seismic properties of the mantle.

One of the principal tools I use in my research is infrared (IR) spectroscopy. Infrared spectroscopy is sensitive to the vibrations of hydrous species (H2O, OH, and NH4+, for example). Electron microprobe and oxygen isotopic analyses are often important components in my research. I also use nuclear magnetic resonance (NMR) spectroscopy, Raman spectroscopy, optical spectroscopy, and X-ray diffraction techniques.

Students

Clinton Colasanti, MS (co-advisor Craig Manning), UCLA: experimental calibration of the OH-in-rutile oxybarometer
Gina Rogers, undergraduate, UCLA: rutile in mantle xenoliths
Miguel Cruz, undergraduate, UCLA: rutile in mantle xenoliths

Current and Recent Research Projects

Hydroxyl in rutile as an oxygen and water barometer

Feldspars as time capsules of magmatic water content from the 1980-1981 eruptions of Mount St. Helens

Diffusion of hydrogen in plagioclase

 

Water and interlayer cations in the manganese oxide mineral birnessite

 

The Hope diamond as a p-type semiconductor

A record of water activity during peak and post granulite-facies metamorphism in the Adirondacks Highlands, NY

 

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